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What is silver oxide?

Silver oxide

One of the most used concepts in the field of chemistry is oxide , a type of chemical compound that can be obtained when a metal, in this case silver (Ag), reacts to the presence of oxygen . There are several types of oxide, for example silver oxide.

Silver oxide |  What is it, characteristics, structure, properties, formulaWhat is silver oxide?

The silver oxide is a type of chemical compound , a fine powder of black or brown which is formed at the time the silver binds with oxygen .

  • Silver oxide characteristics
  • Structure
  • Formula
  • Nomenclature
  • Silver oxide physical properties
  • Chemical properties
  • Obtaining
  • Silver oxide uses
  • Risks

Silver oxide characteristics

The main characteristics that can be found in silver oxide are the following:

  • It is a type of chemical compound that is usually black or very dark brown in color .
  • It can be easily produced for commercial use .
  • It is a type of binary oxide .
  • It is shaped like a three  dimensional polymer .
  • It joins through ionic covalent bonds .
  • It is basically made up of two elements, silver , which has a valence of 1 and oxygen, which has a valence of 2.
  • It works mainly with valence +1 which makes it very stable when it loses an electron in its electronic configuration .

Structure

Regarding its chemical structure , silver oxide, being of the binary type , has a three-dimensional type structure which is joined by means of covalent bonds within its structure. The ions of AG + and 0 2 are in this type of link in a ratio of 2: 1 and are also exposed to a type of electrostatic attraction . It has also been identified ions Ag + has flat square geometries .

Silver oxide - structure

Formula

The chemical formula for silver oxide is Ag2O .

Nomenclature

Regarding its nomenclature, it is done as follows:

  • Systematic nomenclature: diplate monoxide
  • Stock nomenclature: silver oxide
  • Traditional nomenclature: silver oxide

Regarding its nomenclature, it is important to know that, from the moment in which the Ag 2+ and Ag 3+ ions were introduced to the term, the nomenclature changed. Considering that Ag 2+ is very unstable, which makes it almost non-existent, those ions that have +1 and +3 valences are taken into account , in other words Ag (I) and Ag (III).

In the case of the valences I and III and since Ag (I) is the one with the lowest valence, it must be named by adding the suffix -oso to the argentum name . So Ag 2 O is known as argentous oxide ( diplate monoxide). The Ag (III) has the highest valency and therefore, it is added the -ic suffix intone, the AG 2 O 3 is known as a silver oxide .

Silver oxide physical properties

Silver oxide has several physical properties which are:

  • It has the ability to form through a process that is considered thermodynamically reversible .
  • Silver oxide has a density that reaches 7140 Kg / m3.
  • Its molar mass is 231.735 g / mol.
  • It has a melting point when exposed to temperatures of 277ºC.
  • Its solubility is practically nil due to the fact that the spheres that are part of its structure hardly differ in size and for this reason, only tiny molecules can enter the interior of the network.

Chemical properties

The following are the properties that silver oxide possesses:

  • It has an electron configuration of [Kr] 4d8.
  • They are compounds that contain at least one oxygen anion and one metal cation.
  • They are usually insoluble in aqueous solutions (water) and are also extremely stable .
  • Metal oxide compounds are basihydrides and therefore have the ability to react with acids and strong reducing agents in redox reactions .
  • Reacts dangerously with ammonia . Melting silver oxide with metal sulfides, selenium , sulfur, or phosphorus can cause ignition . It is also incompatible with hydrazines, amines, sulfur, metallic sulphides and carbon monoxide.

Obtaining

The way to get the silver oxide is by the combination of aqueous solutions of silver nitrate with an alkali hydroxide .

Silver oxide uses

One of the main uses of silver oxide is to dissolve it in ammonia in order to produce the Tollens reagent , which is a reagent that works perfectly to perform different types of qualitative analysis in organic chemistry laboratories . When mixed with metallic zinc it can form primary zinc-silver oxide batteries , and this is the most common use for silver oxide as it is found in homes and businesses.

It is also used as a type of gas purifier as it is responsible for absorbing carbon dioxide, then when heated, it has the ability to release the gases that it managed to trap in the process and can be used again. Thanks to the antimicrobial properties owned by the silver , one of its components, this oxide is widely used in different studies bioassays and to purify the soil.

It functions as a type of antioxidant agent that has the ability to oxidize aldehydes and is also used as a component in the Hofmann reaction, also participating as a type of reagent or catalyst in various organic type reactions. In alloys for welding , in electrical contacts and even in alloys to make dental pieces , silver oxide can also be used.

Risks

Silver oxide is a strong oxidant and for this reason it can cause various health risks. When it comes into contact with the eyes, it can cause significant irritation as well as burns to the eyeballs. On the skin , it can also cause irritation and burns. If this oxide is ingested , it can become potentially dangerous, causing severe damage to the entire gastrointestinal system , vomiting , nausea, and burns .

When inhaled , the respiratory system is severely affected causing burning in the nose and throat, continuous coughing, breathing difficulties and in more severe cases, pulmonary edema . The chronic inhalation of this product may trigger a pneumoconiosis.

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